The percentage of carbon dioxide (or CO2) in the atmosphere is about 0.0387%, or 0.04% when rounded off. Though it is important to note that carbon dioxide can concentrate itself in certain areas--such as hot springs and urban areas, where it is produced heavily by cars and factories, and there are less plants to turn it back into oxygen. In such areas, concentrations of this gas can reach up to 10 times the normal amount. This 0.04% doesn't sound like much, until you compare it to statistics from before/during the beginning of the industrial revolution that begun in the late 1700s and early 1800s. Since then, the amount of C02 in the air has risen by about 35% to 36%, depending on what sources you quote.
It also might be important to note that CO2 isn't ALL bad! Plants use carbon dioxide in photosynthesis, making the gas necessary to their survival and longevity. In turn, they switch the CO2 back into oxygen to help us breathe.